Anomeric Effect ·
axial beats equatorial at C1
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.com · 2-methoxytetrahydropyran · n(O5)→σ*(C1–X)
ΔG axial
—
³J H1–H2
—
operation
—
ring carbons / C1
ring oxygen O5 (lone pairs)
σ*(C1–X) acceptor · methoxy X
n→σ* donation (axial only)
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.com · The Anomeric Effect