Coenzyme B12 Radical Catalysis · The Homolysis of the Cobalt-Carbon Bond
unseel.com · adenosylcobalamin · Co–C · Ado•
cobalt Co(III) d⁶
Co–C bond intact
species AdoCbl
step
cobalt / corrin
Co–C σ-bond
5′-deoxyadenosyl Ado•
substrate radical
Unseel.com · Coenzyme B12 Radical Catalysis Unseel.com · Coenzyme B12 Radical Catalysis — Concepts