Hiyama Coupling ·
Silicon, Fluoride, One C–C Bond
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.com · R–Si(OMe)₃ + Ar–I → R–Ar · tin-free
Pd state
Pd⁰
Si coord
4
Stage
reagents assembled
Pd metal
Aryl from silane (R)
Aryl halide (Ar)
Silicon (Si)
Fluoride (F⁻)
Iodide (I⁻)
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