Oxy-Cope ·
Anionic [3,3] Shift
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seel
.com · 3-hydroxy-1,5-diene → δ,ε-enone · up to 10¹⁷×
O state
O-H
Rate boost
1×
Stage
3-hydroxy-1,5-hexadiene
Carbon skeleton
Oxygen (O-H / O⁻)
Breaking C3-C4 σ bond
Forming C1-C6 σ bond
π electrons in flight
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.com · Oxy-Cope Rearrangement