Nuclear Physics

Half-Life

Time for half a radioactive sample to decay — exponential, immutable, intrinsic to each isotope

Half-life (τ_½) is the time for half of a radioactive sample's nuclei to decay. Constant for each isotope — independent of temperature, chemistry, or amount. C-14: 5730 yr. U-238: 4.5 Gyr. Tc-99m: 6 hr. After n half-lives, fraction remaining = (1/2)ⁿ. Foundation of radiometric dating, medical isotope dosing, nuclear waste management.

  • DefinitionTime for N → N/2
  • Mathematical relationτ_½ = ln(2) / λ ≈ 0.693 / λ
  • IndependenceConstant; not affected by T, P, chemistry
  • After n half-livesFraction = (1/2)ⁿ
  • Range observed10⁻²⁴ s to 10²⁴ years
  • OriginQuantum mechanical; exponential by Poisson statistics

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Formula

Number remaining at time t:

N(t) = N₀ · e^(-λt) = N₀ · (1/2)^(t/τ_½)

where τ_½ = ln(2)/λ ≈ 0.693/λ.

Activity (decays/sec):

A(t) = λ · N(t) = A₀ · e^(-λt)

Mean lifetime (average for individual nucleus):

τ_mean = 1/λ = τ_½ / ln(2) ≈ 1.443 · τ_½

Famous half-lives

IsotopeHalf-lifeDecay modeUse
Po-2120.3 µsα
F-18110 minβ⁺ → O-18PET imaging
Tc-99m6 hrγ → Tc-99SPECT (most common medical)
I-1318 daysβ⁻ → Xe-131Thyroid therapy/diagnostics
Co-605.27 yrβ⁻ → Ni-60Cancer therapy, sterilization
Tritium (H-3)12.3 yrβ⁻ → He-3Glow-in-dark, fusion fuel
Sr-9028.8 yrβ⁻ → Y-90Reactor accident contaminant
Cs-13730.2 yrβ⁻ + γ → Ba-137Reactor accident contaminant
Ra-2261600 yrα → Rn-222Used to define curie
C-145,730 yrβ⁻ → N-14Carbon dating
Pu-23924,100 yrα → U-235Weapons, reactor fuel
U-2357 × 10⁸ yrα → Th-231Reactor fuel
U-2384.5 × 10⁹ yrα → Th-234Most natural U; dating
Bi-2092 × 10¹⁹ yrα → Tl-205"Stable" until 2003
Te-1282.2 × 10²⁴ yr2β⁻ → Xe-128Longest known half-life

JavaScript — half-life calculations

// Number remaining after time
function fractionRemaining(t, halfLife) {
  return Math.pow(0.5, t / halfLife);
}

// Number after n half-lives
function afterNHalfLives(N_0, n) {
  return N_0 / Math.pow(2, n);
}

console.log(`After 5 half-lives: ${(fractionRemaining(5, 1) * 100).toFixed(2)}%`);  // 3.13%
console.log(`After 10 half-lives: ${(fractionRemaining(10, 1) * 100).toFixed(4)}%`); // 0.0977%

// Solve for age given fraction
function ageFromFraction(fraction, halfLife) {
  return -halfLife * Math.log(fraction) / Math.log(2);
}

console.log(`75% C-14 left: ${ageFromFraction(0.75, 5730).toFixed(0)} yr`); // ~2378
console.log(`50%: ${ageFromFraction(0.50, 5730).toFixed(0)} yr`);          // 5730
console.log(`10%: ${ageFromFraction(0.10, 5730).toFixed(0)} yr`);          // 19035

// Activity from mass
function activityFromMass(mass_g, atomicMass, halfLife_s) {
  const N = mass_g / atomicMass * 6.022e23;
  const lambda = Math.log(2) / halfLife_s;
  return N * lambda;  // Bq
}

// 1 µg of Tc-99m
const Tc_halflife = 6 * 3600;  // 6 hours in seconds
const Tc_activity = activityFromMass(1e-6, 99, Tc_halflife);
console.log(`1 µg Tc-99m: ${(Tc_activity / 1e6).toFixed(2)} MBq`);

// Decay chain (parent-daughter)
function parentDaughterRatio(t, lambda_p, lambda_d) {
  // Bateman equation for daughter from parent
  // N_d/N_p = lambda_p/(lambda_d - lambda_p) · (1 - exp(-(lambda_d - lambda_p)t))
  if (Math.abs(lambda_p - lambda_d) < 1e-15) return lambda_p * t;
  return lambda_p / (lambda_d - lambda_p) * (1 - Math.exp(-(lambda_d - lambda_p) * t));
}

// Multi-isotope mixture: total activity is sum
function mixedActivity(isotopes, t) {
  return isotopes.reduce((sum, iso) => {
    const remaining = iso.N_0 * Math.pow(0.5, t / iso.halfLife);
    return sum + remaining * Math.log(2) / iso.halfLife;
  }, 0);
}

// Carbon dating: charcoal sample, 25% C-14 remaining
const sampleAge = ageFromFraction(0.25, 5730);
console.log(`Sample age: ${sampleAge.toFixed(0)} years`);

Where half-life matters

  • Radiometric dating. C-14 for organics < 50,000 yr; U-Pb for rocks billions of years.
  • Medical isotopes. Match half-life to medical procedure timing.
  • Nuclear waste. Spent fuel needs storage for many half-lives of dangerous isotopes.
  • Drug pharmacokinetics. Biological half-life concept (different — drug clearance, not radioactive).
  • Smoke detectors. Am-241 (433 yr) — long enough to last lifetime of detector.
  • Industrial gauging. Cs-137 (30 yr) typical for thickness gauges.
  • Particle physics. Particle lifetimes characterized by half-life or mean lifetime.

Common mistakes

  • Linear vs exponential. After 2 half-lives, 25% remains, NOT 0%. Exponential decay never reaches zero.
  • Confusing half-life with mean lifetime. Mean = 1.443 × half-life. Mean is the AVERAGE time per particle; half-life is when half of population gone.
  • Believing temperature affects half-life. NO — nuclear, not chemical. Decay rate same at any T (with rare exceptions like Be-7 EC).
  • Using "100 hour quarantine" for safety. 100 hours isn't safe relative to half-life. Need 5-10 half-lives for activity to drop to negligible.
  • Treating "stable" as forever. Some "stable" isotopes have actually been observed to decay (Bi-209 has 2 × 10¹⁹ yr half-life). True stability is rare.
  • Confusing physical and biological half-life. Physical half-life — radioactive decay. Biological — clearance from body. Effective half-life combines both — usually shorter than physical.

Frequently asked questions

Why is decay exponential?

Each unstable nucleus has a constant probability per unit time of decaying — independent of when it formed. With N nuclei, average decays/sec = λN (proportional to N). Solution: N(t) = N₀·e^(-λt). This is Poisson process: random, independent events with rate λ. Half-life follows directly.

How is half-life independent of conditions?

Decay is a NUCLEAR property — depends on internal nuclear structure. Chemistry and temperature affect electrons, not nuclei. So a hot uranium sample decays at the same rate as a cold one. Same chemical compound has same isotope half-life. Pressure, magnetic fields, etc. — same. (Tiny exceptions exist for electron-capture decays in some chemistries.)

What's the range of observed half-lives?

From ~10⁻²⁴ seconds (some excited nuclear states; resonances) to ~10²⁴ years (Tellurium-128). Most familiar isotopes have half-lives in nanoseconds to billions of years. Polonium-212: 0.3 µs. Tritium: 12.3 yr. Carbon-14: 5730 yr. Uranium-238: 4.5 Gyr. Bismuth-209: 2 × 10¹⁹ yr (longer than universe age!).

How is half-life used in dating?

Carbon-14 dating — atmospheric C-14/C-12 ratio constant; living things absorb this; after death, C-14 decays. Measure remaining ratio, compute age. Range 0-50,000 years (limited by tiny C-14 amounts). For older — uranium-lead (U-238 to Pb-206), potassium-argon (K-40 to Ar-40), rubidium-strontium. Earth's age determined this way.

How are half-lives chosen for medical use?

Match to medical procedure. Tc-99m (6 hr) — perfect for diagnostic imaging (long enough to image, short enough to clear from body). I-131 (8 days) — thyroid therapy. F-18 (110 min) — PET imaging (must produce on-site). Long half-life isotopes (Cs-137, Co-60) — external beam therapy. Avoid extremes — too short doesn't transport; too long lingers in body.

What if a sample contains multiple isotopes?

Each decays exponentially. Total = sum of individual exponentials. After long time, only longest half-life remains. "Burn-in" period — short half-life isotopes decay first; activity drops. Fission products show this — initial high activity from short-lived, then dominated by longer-lived (Sr-90, Cs-137) for decades, then by very long (radioactive technetium etc.).

How precisely are half-lives measured?

Very precisely. Some half-lives known to 6+ significant figures. Methods: count decays vs time; measure mass ratios in chains; isotope decay sequencing. Standards: NIST reference values. Specialized work for very long (background subtraction critical) and very short (instrumentation challenges).